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  3. Polymer Modified Bitumen (PMB)

Wiki

Polymer Modified Bitumen (PMB)

General Description

Polymer Modified bitumen (PMB) is one of the specially designed and engineered bitumen grades that are used in making pavement, roads for heavy-duty traffic, and home roofing solutions to withstand extreme weather conditions. This material is also used as a sealant in residential roofing applications.

consists of bitumen blended with a synthetic polymer or crumb rubber. PMBs are used to enhance the performance of binders on heavily trafficked or distressed pavement surfaces, often in adverse climatic conditions. Property improvements include reduced temperature susceptibility, increased elasticity or resilience, increased cohesion, and improved tenacity once a bond has been established. as a valued engineering material continues to increase. The interest in the modification of bitumen using polymers, whether virgin, scrap, or polymer blends, is intense.

Production of hot asphalt mixes with Polymer modified Bitumen (PMB) is mandatory for enhancing the performance of bitumen used in road, runway, and racetrack applications both by improving life expectancy and reducing maintenance levels.

There are 4 important issues for good quality PMB:

Bitumen quality, polymer compatibility (the most used polymer is SBS), mill performance (a high-quality mill with high power is fundamental to grant the perfect blending of polymer and bitumen), and good agitation of the final product (which is guaranteed by two agitators in each tank).

However, it is brittle in cold environments and softens readily in warm environments. One of the many methods employed to toughen bitumen is to blend it with polymers, either virgin or scrap, to produce (PMB) . A lowering of the breaking point (DIN 52 012) and an increase in ductility (DIN 52 013) by polymer additive show better cold flexibility and are called polymer modified bitumen.

Composition of Polymer Asphalts

Composition of polymer modified bitumen is bitumen plus polymer and a compatibilizing agent prepared by reacting one or more unsaturated monomers with a bituminous composition comprising asphaltenes or resins.

Asphaltenes and resins are two of four broad component groups found in bitumen (the others are aromatics and saturates; resins, aromatics, and saturates are collectively known as maltenes). Asphaltites are n-heptane insoluble black or brown amorphous solids and are generally considered to be highly polar and complex aromatic materials of fairly high molecular weight.

Resins are soluble in n-heptane and are typically dark brown in color, solid or semi-solid, and polar. In one embodiment of the invention, the bituminous composition comprising asphaltenes and/or resins is a bituminous composition comprising all four components, i.e. resins, aromatics, saturates and asphaltenes.

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PMB Production Process

Manufacturing of PMB starts with preparation of the raw materials. Bitumen is heated up to 170-180° C in service tanks; pre-weighed polymer bags are placed near the feeding screw as per the production specification.

Bitumen is pumped into weighing and mixing tanks, and the polymer is added using metering systems. The operator ensures the polymer is fully loaded, and the PLC control system verifies the bitumen and polymer quantities before mixing. The polymer-bitumen mixture is pumped through a high shear mill to ensure thorough disintegration for quality modification. A 160 kW high shear mill is recommended for high-quality PMB.

During production, one tank is filled while another is processed, thus allowing for continuous operation controlled by PLC.

Storage: PMB blends are stored in special agitation tanks at 160-180°C. Stirring is periodically performed to avoid polymer agglomeration and maintain blend stability. During asphalt production, PMB must be stirred or recirculated to ensure proper mixing.

Application of Polymer Modified Bitumen

Polymer Modified Bitumen can be used in asphalt mix designs which results in the manufacture of cohesive asphalt mix with good elasticity suitable for type of traffic. Special attention to be taken to the temperatures while manufacturing, lying and compaction are performed.

  • Higher rigidity
  • Increased resistance to deformation
  • Increased resistance to cracks and stripping
  • Better water resistance properties
  • High durability

Specification of Polymer Modified Bitumen (PMB)

PropertyUnitsPMB 10/40-70PMB 25/55-65PMB 45/80-60
PMB 45/80-65PMB 45/80-75PMB 75/130-60Test Method UNE-EN
Penetration @25°C0.1mm10-4025-5525-5545-8045-8075-1301426
Softening point°C≥ 70≥ 65≥ 60≥ 65≥ 75≥ 601427
Cohesion. Strength-ductilityJ/cm2≥ 2 a 15ºC≥ 2 a 15ºC≥ 2 a 15ºC≥ 2 a 15ºC≥ 2 a 15ºC≥ 2 a 15ºC13589
13703
Fraass breaking point°C≤ -5≤ -7≤ -12≤ -15≤ -15≤ -1512593
Elastic recovery at 25ºC%TBR≥ 50≥ 50≥ 70≥ 80≥ 6013398
Stability in storage
Difference in
softening point
°C≤ 5≤ 5≤ 5≤ 5≤ 5≤ 513399
1427
Stability in storage
Difference in
penetration poin
0.1mm≤ 9≤ 9≤ 9≤ 9≤ 13≤ 1313399
1426
Flash point°C≥ 235≥ 235≥ 235≥ 235≥ 235≥ 220ISO 2592
Resistance to Hardening @163°C
Change of mass%≤ 0.8≤ 0.8≤ 1.0≤ 1.0≤ 1.0≤ 1.012607-1
Retained penetration%≥ 60≥ 60≥ 60≥ 60≥ 60≥ 601426
Increase in softening point°C≤ 8≤ 8≤ 10≤ 10≤ 10≤ 101427
Decrease in softening point°C≤ 5≤ 5≤ 5≤ 5≤ 5≤ 51427

Polymer Modified Bitumen Technical Datasheet

DesignationPMB 40PMB 70PMB 120Test Method
Penetration at 25 ֯C, 1/10mm, 100g, 5 sec30-5050-9090-150ASTM D5
Softening Point, (R&B), ֯C, Min605550ASTM D36
Elastic Recovery at 15 ֯C ,%, Min606060ASTM D6084
Flash point , COC, ֯C , Min220220220ASTM D92
Separation, Difference in Softening Point,(R&B), ֯C, Max333–
Thin Film Oven Test & Test on Residue
Loss in Mass, %, Max1.01.01.0ASTM D1754
Reduction in Penetration of residue at 25 ֯C , 100g, 5s, %,Max353535ASTM D5
Increase in Softening Point, ֯C, Max567ASTM D36
Elastic Recovery at 25 ֯C, %, Min505050ASTM D6085

Contact

Dubai Office: No. 2305 of the Burlington Tower, Business Bay, DUBAI-UAE
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Postcode 068 30
Tell: +90 312 544 5481
Mob:+90 555 160 5739 (WhatsApp)
Mob: +90 552 806 9131(WhatsApp)
Iran Office: Second Floor, Navab Complex, Navab Safavi St, Esfahan-Iran
Mob: +98 913 310 7534 (whatsapp)
Mob: +98 913 205 0036 (whatsapp)
Tell: +98 31 32355207
Email: info@bitumenoxidised.com


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